Visualization of Phase Evolution of Ternary Spinel Transition Metal Oxides (CuFe2O4) during Lithiation
نویسندگان
چکیده
منابع مشابه
Phase Transition in Mixed Transition Metal Oxides under High Pressure
Mixed crystals can be categorized as the crystal in which two or more different types of atoms are present and configured. These atoms interact each other in the influence of Coulomb force of attraction and the presence of short range repulsion force. Due to this interaction they tends to be arranged in equilibrium state and forms new material. A pure crystal can be doped by impurities with pro...
متن کاملEvolution of photoemission spectral functions in doped transition metal oxides
We discuss the experimental photoemission and inverse photoemission of early transition metal oxides, in the light of the dynamical mean field theory of correlated electrons which becomes exact in the limit of infinite dimensions. We argue that a comprehensive description of the experimental data requires spatial inhomogeneities and present a calculation of the evolution of the spectral functio...
متن کاملVisualizing non-equilibrium lithiation of spinel oxide via in situ transmission electron microscopy
Spinel transition metal oxides are important electrode materials for lithium-ion batteries, whose lithiation undergoes a two-step reaction, whereby intercalation and conversion occur in a sequential manner. These two reactions are known to have distinct reaction dynamics, but it is unclear how their kinetics affects the overall electrochemical response. Here we explore the lithiation of nanosiz...
متن کاملElectroplating lithium transition metal oxides
Materials synthesis often provides opportunities for innovation. We demonstrate a general low-temperature (260°C) molten salt electrodeposition approach to directly electroplate the important lithium-ion (Li-ion) battery cathode materials LiCoO2, LiMn2O4, and Al-doped LiCoO2. The crystallinities and electrochemical capacities of the electroplated oxides are comparable to those of the powders sy...
متن کاملINFLUENCE OF THE PREPARATION METHOD ON THE STRUCTURE,PHASE FORMATION AND MAGNETIC PROPERTIES OF TEMPLATED CUFE2O4 SPINEL
The synthesis of mesoporous CuFe2O4 spinel by several nanocasting strategies (i.e., multi-step nanocasting, one step nanocasting, modified solid-liquid), in which copper and iron nitrates are used as precursors and Pluronic P123 as surfactant, is explored. We have also checked the effect of pH, citric acid and sodium citrate in multi-step nanocasting method. The modified solid-liquid method whi...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Microscopy and Microanalysis
سال: 2017
ISSN: 1431-9276,1435-8115
DOI: 10.1017/s1431927617010777